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Titel:
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The Conceptual Design of a Continuous Pervaporation Membrane Reactor for the Production of 1,1-Diethoxy Butane
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Auteur(s):
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Agirre, I.; Belen Guemez, M.; Motelica, A.; Veen, H.M. van; Vente, J.F.; Arias, P.L.
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Gepubliceerd door:
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Publicatie datum:
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ECN
Efficiency & Infrastructure
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4-11-2011
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ECN publicatienummer:
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Publicatie type:
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ECN-W--11-056
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Artikel wetenschap tijdschrift
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Aantal pagina's:
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8
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Gepubliceerd in: AIChE Journal (Wiley), , 2011, Vol.online, p.-.
Samenvatting:
Acetals are considered as an important bio-based diesel additives. Generally, the catalytic production of these compounds from an alcohol and an aldehyde suffers from a low conversion because of thermodynamic limitations. These limitations can be overcome through the in situ removal of the by-product water using, for example, a water selective membrane. A critical evaluation on the membrane performance, catalyst activity, optimal configuration, and feed composition leads to the conclusion that a combined reaction and separation is unlikely to be advantageous. The water permeance of the selected membrane was assessed to be too low in relation with the catalyst activity.
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